科院考研推荐链接:
将高分辨率质谱与光参量振动激光器、极紫外自由电子激光、红外自由电子激光相结合,发展红外光解离光谱和光电子能谱等实验方法,分子水平上研究催化基元反应机理和雾霾成因机理。已在JACS、Angew. Chem. Int. Ed.等国际核心期刊发表论文100余篇。
研究方向包括:
(1) 催化基元反应机理 (Structure-reactivity Relationship)
催化剂表面活性中心的组成及其与关键反应中间体之间键合结构的表征是诠释催化作用机制的关键。然而,这些物种的数量密度很低,并且不能长时间稳定存在,因此对这些反应中间体的结构和动力学性质研究需要高灵敏、瞬态探测实验方法。我们首先采用高分辨反射式飞行时间质谱仪捕捉反应中间体,再利用高灵敏度的红外光解离光谱和光电子能谱等先进光谱方法,表征这些关键物种的几何结构和电子结构,揭示反应机制。
(2) 雾霾成因机理研究 (Atmospheric Chemistry)
大气环境污染已经给人类的健康和交通安全等方面造成了严重的危害,治理和调控雾霾迫在眉睫。而从根本上理解大气雾霾的形成和生长机理对于治理大气污染的防治非常重要。大气中的化学物质与水分子作用后,形成分子团簇,这些团簇在生长过程中吸附各种污染分子以及水分子,生长为较大的气溶胶颗粒,并逐渐成长为雾霾。
由于在大气条件下从分子形成分子团簇是气溶胶形成机理的关键步骤,所以,分子团簇化学成份与结构的测定对理解凝聚成核过程机理和控制大气颗粒物污染具有指导意义。利用大连相干光源极紫外软电离技术,通过发展高灵敏度的单颗粒气溶胶质谱和成核机理,解析大气化学中性团簇的精细结构,揭示气溶胶的成核动力学机制。
研究方法:
(1)实验方法:红外光解离光谱、红外-极紫外双共振光谱、光电子能谱
(2)理论方法:量子化学计算,分子动力学模拟
2011.8-今 中科院大连化学物理研究所 分子反应动力学国家重点实验室,团簇光谱与动力学研究组组长,研究员(****)
2009-2011 德国马普协会Fritz-Haber研究所,洪堡学者
2007-2009 日本产业技术综合研究所,日本学术振兴会博士后
获奖信息:
(1)2013-2016 中国科学院****择优支持
(2)2009-2011 德国洪堡协会博士后奖学金
(3)2007-2009 日本学术振兴会博士后奖学金
(4)2005-2007 日本文部省奖学金
(5)2005-2006 日本丸文研究交流财团基金
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2019 |
105. |
Probing solvation and reactivity in ionized polycyclic aromatic hydrocarbon-water clusters with photoionization mass spectrometry and electronic structure calculations Bo Xu, Tamar Stein, Utuq Ablikim, Ling Jiang, Josie Hendrix, Martin Head-Gordon, and Musahid Ahmed* Faraday Discussions, 2019, DOI: 10.1039/c8fd00229k. |
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104. |
Electrospray ionization photoelectron spectroscopy of cryogenic [EDTA•M(II)]2− complexes (M = Ca, V−Zn): electronic structures and intrinsic redox properties Qinqin Yuan, Xiangtao Kong, Gao-Lei Hou, Ling Jiang,* and Xue-Bin Wang* Faraday Discussions, 2019, DOI:10.1039/c8fd00175h. |
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103. |
Structures and Infrared Spectra of [M(CO2)7]+ (M = V, Cr, Mn) Complexes Dong Yang, Xiangtao Kong, Huijun Zheng, Mingzhi Su, Zhi Zhao, Hua Xie, Hongjun Fan, Weiqing Zhang, and Ling Jiang* J. Phys. Chem. A 2019, 123, 3703–3708. |
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102. |
Infrared Photodissociation Spectroscopic and Theoretical Study of [Co(CO2)n]+ Clusters Dong Yang, Mingzhi Su, Huijun Zheng, Zhi Zhao, Gang Li, Xiangtao Kong, Hua Xie, Hongjun Fan, Weiqing Zhang, and Ling Jiang* Chin. J. Chem. Phys. 2019, 32, 223-228. |
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101. |
Size-Dependent Formation of an Ion Pair in HSO4−(H2O)n: A Molecular Model for Probing the Microsolvation of Acid Dissociation Huiyan Li, Xiangtao Kong, Ling Jiang,* and Zhi-Feng Liu* J. Phys. Chem. Lett., 2019, 10, 2162–2169. |
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100. |
Ligand-Mediated Reactivity in CO Oxidation of Niobium-Nickel Monoxide Carbonyl Complexes: The Crucial Roles of the Multiple Adsorption of CO Molecules Jumei Zhang, Ya Li, Zhiling Liu,* Gang Li, Hongjun Fan, Ling Jiang,* and Hua Xie* J. Phys. Chem. Lett., 2019, 10, 1566-1573. |
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99. |
Infrared spectra of neutral dimethylamine clusters: An infrared-vacuum ultraviolet spectroscopic and anharmonic vibrational calculation study Bingbing Zhang, Qian-Rui Huang, Shukang Jiang, Li-Wei Chen, Po-Jen Hsu, Chong Wang, Ce Hao, Xiangtao Kong, Dongxu Dai, Xueming Yang, Jer-Lai Kuo,* and Ling Jiang* J. Chem. Phys. 2019, 150, 064317. |
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2018 |
98. |
Geometric Structures and Magnetic Interactions in Small Chromium Oxide Clusters Le Nhan Pham, Pieterjan Claes, Peter Lievens, Ling Jiang, Torsten Wende, Knut R. Asmis, Minh Tho Nguyen,* and Ewald Janssens* J. Phys. Chem. C 2018, 122, 27640-27647. |
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97. |
Infrared Photodissociation Spectroscopy of Ion-Radical Networks in Cationic Dimethylamine Complexes Xin Lei, Xiangtao Kong, Zhi Zhao, Bingbing Zhang, Dongxu Dai, Xueming Yang, and Ling Jiang* Phys. Chem. Chem. Phys. 2018, 20, 30125-30132. (Featured on Front Cover) |
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96. |
Solvation effects on the N−O and O−H stretching modes in hydrated NO3−(H2O)n clusters Huiyan Li, Xiangtao Kong, Ling Jiang,* and Zhi-Feng Liu* Phys. Chem. Chem. Phys. 2018, 20, 26918-26925. |
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95. |
Temperature-Dependent Infrared Photodissociation Spectroscopy of (CO2)3+ Cation Xin Lei, Xiangtao Kong, Bingbing Zhang, Zhi Zhao, Dongxu Dai, Xueming Yang, and Ling Jiang* J. Phys. Chem. A 2018, 122, 8054-8057. |
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94. |
Photoelectron Velocity Map Imaging Spectroscopic and Theoretical Study of Heteronuclear Vanadium-Nickel Carbonyls VNi(CO)n– (n = 2-6) Qinqin Yuan, Jumei Zhang, Jinghan Zou, Hongjun Fan, Ling Jiang,* and Hua Xie* J. Chem. Phys. 2018, 149, 144305. |
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93. |
Magnetic-bottle and velocity-map imaging photoelectron spectroscopy of APS− (A = C14H10 or anthracene): electron structure, spin-orbit coupling of APS•, and dipole-bound state of APS− Qinqin Yuan, Zheng Yang, Renzhong Li, Wesley J. Transue, Zhipeng Li, Ling Jiang, Niranjan Govind, Christopher C. Cummins,* and Xue-Bin Wang* Chin. J. Chem. Phys. 2018, 31, 463-470. |
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92. |
Infrared Photodissociation Spectroscopy of Cold Cationic Trimethylamine Complexes Xin Lei, Xiangtao Kong, Zhi Zhao, Bingbing Zhang, Dongxu Dai, Xueming Yang, and Ling Jiang* Phys. Chem. Chem. Phys. 2018, 20, 25583-25591. (Featured on Back Cover) |
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91. |
Photoelectron Spectroscopic and Computational Study of [EDTA•M(III)]− Complexes (M = H3, Al, Sc, V−Co) Qinqin Yuan, Xiang-Tao Kong, Gao-Lei Hou, Ling Jiang,* and Xue-Bin Wang* Phys. Chem. Chem. Phys. 2018, 20, 19458-19469. |
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90. |
Coordination-Induced CO2 Fixation into Carbonate by Metal Oxides Zhi Zhao, Xiangtao Kong, Qinqin Yuan, Hua Xie, Dong Yang, Jijun Zhao, Hongjun Fan,* and Ling Jiang* Phys. Chem. Chem. Phys. 2018, 20, 19314-19320. (Featured on Back Cover) |
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89. |
Solvation Effects on the Vibrational Modes in Hydrated Bicarbonate Clusters Xiangtao Kong, Shou-Tian Sun, Ling Jiang,* and Zhi-Feng Liu* Phys. Chem. Chem. Phys. 2018, 20, 4571-4578. |
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88. |
Ligand-Enhanced CO Activation by the Early Lanthanide-Nickel Heterodimers: Photoelectron Velocity-Map Imaging Spectroscopy of LnNi(CO)n- (Ln = La, Ce) Gang Li, Jumei Zhang, Hua Xie, Xiangtao Kong, and Ling Jiang* J. Phys. Chem. A 2018, 122, 3811-3818. |
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87. |
Photoelectron Velocity-map Iimaging and Theoretical Studies of Heterotrinuclear Metal Carbonyls V2Ni(CO)n− (n= 6-10) Jumei Zhang, Hua Xie, Gang Li, Xiangtao Kong, Qinqin Yuan, Jinghan Zou, Hongjun Fan, and Ling Jiang* J. Phys. Chem. A 2018, 122, 53-59. |
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86. |
Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal-nickel Carbonyls MNi(CO)n– (M = Sc, Y; n = 2-6) Hua Xie, Jinghan Zou, Qinqin Yuan, Jumei Zhang, Hongjun Fan, and Ling Jiang* Topics in Catalysis, 2018, 61, 71-80. (Invited article for special issue “Size-Selected Clusters as Model Systems for Catalysis”.) |
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85. |
On the Solvation of Hydronium by Carbon Dioxide: Structural and Infrared Spectroscopic Study of (H3O+)(CO2)n Jianpeng Yang*, Xiangtao Kong, and Ling Jiang* Chem. Phys. 2018, 501, 1-7. |
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2017 |
84. |
Infrared-Vacuum Ultraviolet Spectroscopic and Theoretical Study of Neutral Trimethylamine Dimer Bingbing Zhang, Xiangtao Kong, Shukang Jiang, Zhi Zhao, Hua Xie, Ce Hao, Dongxu Dai, Xueming Yang, and Ling Jiang* Chin. J. Chem. Phys. 2017, 30, 691-695. |