加入25年中科院考研群 加入25年中科大考研群
中国科学院上海有机化学研究所唐勇 男 博导
 

科院考研推荐链接:

考研资料:中科院考研真题  

考研信息:找个直系学长,咨询考研问题   

考研一对一:学长带队,复习不累

研究领域

后过渡烯烃催化剂的设计、合成及可控性聚合;
主族元素化合物的化学;
不对称催化。

招生信息

   
招生专业
070303-有机化学
招生方向
金属有机化学

教育背景

1993-03--1996-02   上海有机所   博士
1990-09--1993-02   上海有机所   硕士
1982-09--1986-06   四川师范大学化学系   学士学位

工作经历

   
工作简历
2000-01~现在, 上海有机所, 研究员
1999-05~1999-12,上海有机所, 副研究员
1997-06~1999-04,美国 Georgetown University, 博士后
1996-08~1997-05,美国Colorado State University, 博士后
1996-03~1996-07,上海有机所, 助理研究员
1986-07~1990-08,西华大学(原成都师范专科学校化学系), 助教
社会兼职
2006-07--今 International Advisory Board of IUPAC International Conference on Organometallic Chemistry

教授课程

有机合成反应

专利与奖励

   
奖励信息
(1) 庄长恭化学科学技术进步奖,其他级,2014 
(2) 第十三届上海市科技精英提名奖,省级,2013 
(3) 基于边臂策略的立体化学控制与催化反应研究,二等奖,国家级,2012 
(4) 黄耀曾金属有机化学奖,其他级,2012 
(5) 基于边臂策略的立体化学控制与催化反应研究,一等奖,省级,2011 
(6) 朱李月华优秀教师奖,部委级,2009 
(7) 第九届中国青年科技奖,部委级,2006 
(8) 中国科学院研究生院优秀教师,部委级,2006 
专利成果
( 1 ) 烯烃聚合催化剂, 发明, 2013, 第 1 作者, 专利号: ZL 201010108673.0
( 2 ) 一类具有单活性中心性质的齐格勒-纳塔烯烃聚合催化剂, 发明, 2012, 第 1 作者, 专利号: ZL 201010108695.7
( 3 ) 乙烯齐聚催化剂及其用途, 发明, 2012, 第 1 作者, 专利号: ZL 200510025276.6
( 4 ) Catalyst for Polymerization or Copolymerization of Olefins,Preparation and Use of the same, 发明, 2012, 第 4 作者, 专利号: EP 1426385
( 5 ) 负载型非茂金属聚烯烃催化剂、制备方法及用途, 发明, 2013, 第 1 作者, 专利号: ZL 201010288625.4
( 6 ) 负载砷催化剂、合成方法及其在Wittig反应中的用途, 发明, 2013, 第 1 作者, 专利号: ZL 201010559616.4
( 7 ) 一种镍系烯烃聚合催化剂,制备方法和用途, 发明, 2014, 第 1 作者, 专利号: ZL 201110008851.7
( 8 ) 一种镍系烯烃聚合催化剂、制备方法和用途, 发明, 2014, 第 1 作者, 专利号: ZL 201110008851.7
( 9 ) 烯烃聚合催化剂及超低支化度超高分子量聚乙烯, 发明, 2014, 第 1 作者, 专利号: ZL 201010554473.8
( 10 ) 一种烯烃聚合催化剂及超低支化度超高分子量聚乙烯, 发明, 2014, 第 1 作者, 专利号: ZL 201110109882.1
( 11 ) 一类由烯烃制备高支化烷烃的催化体系, 发明, 2015, 第 1 作者, 专利号: ZL 201110126431.9
( 12 ) 一类单中心催化剂在乙烯溶液聚合中的应用, 发明, 2015, 第 1 作者, 专利号: ZL 201110385610.4
( 13 ) 一类烯烃聚合催化剂及超低支化度超高分子量聚乙烯, 发明, 2015, 第 1 作者, 专利号: ZL 201110109884
( 14 ) 新型铬催化剂及其在催化烯烃齐聚和高聚中的应用, 发明, 2014, 第 1 作者, 专利号: ZL 201010509672.7
( 15 ) 一类由烯烃制备高支体系化烷烃的催化, 发明, 2016, 第 1 作者, 专利号: US9315755B2
( 16 ) 烯烃聚合或共聚合催化剂及其制备方法, 发明, 2017, 第 1 作者, 专利号: ZL201110456901.8
( 17 ) 高支化油状烷烃聚合物及其制法和应用, 发明, 2017, 第 1 作者, 专利号: 201210098399.2
( 18 ) 一类由烯烃制备高支化烷烃的催化体系(日本), 发明, 2017, 第 1 作者, 专利号: JP2014-510649
( 19 ) 一类由烯烃制备高支化烷烃的催化体系(日本), 发明, 2017, 第 1 作者, 专利号: JP2016-093507
( 20 ) 一种乙烯极性单体共聚物及其制备方法, 发明, 2018, 第 1 作者, 专利号: 201810570670.5
( 21 ) 一种金属配合物、中间体、其制备方法及应用, 发明, 2018, 第 1 作者, 专利号: 201810579310.1
( 22 ) 7-氨基色满类化合物的不对称制备及应用, 发明, 2018, 第 1 作者, 专利号: 201810541096.0

出版信息

   
发表论文
(1) Catalyst-Controlled Chemoselective All-Alkene [2+2+2] and [2+2] Cyclizations of Enamides with Electron-Deficient Alkenes., Org. Lett., 2019, 通讯作者
(2) Selectivity Switch in a Rhodium(II) Carbene Triggered Cyclopentannulation: Divergent Access to Three Polycyclic Indolines, Angew. Chem. Int. Ed., 2019, 第 6 作者
(3) Synergetic Tandem Enantiomeric Enrichment in Catalytic Asymmetric Multi-Component Reactions (AMCRs): Highly Enantioselective Construction of Tetracyclic Indolines with Four Continuous Stereocenters, ACS Catal., 2018, 通讯作者
(4) Highly Enantioselective [3+2] Annulation of Indoles with Quinones to Access Structurally Diverse Benzofuroindolines, Angew. Chem. Int. Ed., 2018, 通讯作者
(5) Highly Enantioselective Nickel-Catalyzed Oxa-[3 + 3] Annulation of Phenols with Benzylidene Pyruvates for Chiral Chromans, Org. Lett., 2018, 通讯作者
(6) Highly enantioselective cyclopropanation of trisubstituted olefins, Sci China Chem, 2018, 通讯作者
(7) Copper Catalyzed Asymmetric [4+2] Annulations of D‐A Cyclobutanes with Aldehydes, Chin. J. Chem., 2018, 通讯作者
(8) Reaction of Donor-Acceptor Cyclobutanes with Indoles: A General Protocol for the Formal Total Synthesis of (±)-Strychnine and the Total Synthesis of (±)-Akuammicine, Angew. Chem. Int. Ed., 2017, 通讯作者
(9) An Unprecedented Asymmetric Cascade Access to Hexahydro-carbazoles: the Thorpe-Ingold Effects of Ligand on Enantioselectivity, Angew. Chem. Int. Ed., 2017, 通讯作者
(10) Highly Efficient Formal [2+2+2] Strategy for the Rapid Construction of Polycyclic Spiroindolines: AConcise Synthesis of 11-Demethoxy-16- epi-myrtoidine., Angew. Chem. Int. Ed., 2016, 通讯作者
(11) Cy-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals, Angew. Chem. Int. Ed., 2016, 通讯作者
(12) Enantioselective Construction of Cyclobutanes: A New and Concise Approach to the Total Synthesis of Piperarborenine B., J. Am. Chem. Soc., 2016, 通讯作者
(13) Asymmetric Ring-Opening Reactions of Donor-Acceptor Cyclopropanes and Cyclobutanes., Isr. J. Chem., 2016, 通讯作者
(14) Asymmetric H2O-Nucleophilic Ring Opening of D−A Cyclopro-panes: Catalyst Serves as a Source of Water, J. Am. Chem. Soc. 2015, 137, 14594-14597, 2015, 通讯作者
(15) Asymmetric Annulation of Donor-Acceptor Cyclopropanes with Dienes, J.Am.Chem.Soc.,2015, 137, 8006-8009, 2015, 通讯作者
(16) Asymmetric 1,2-Perfluoroalkyl Migration: Easy Access to Enantioenriched alpha-Hydroxy-alpha-perfluoroalkyl Esters, J.Am.Chem.Soc., 2015, 137, 4626-4629, 2015, 通讯作者
(17) Side Arm Strategy for Catalyst Design: Modifying Bisoxazolines for Remote Control of Enantioselection and Related, Acc. Chem. Res., 2014, 47 2260-2272, 2014, 通讯作者
(18) Remote Ester Groups Switch Selectivity: Diastereodivergent Synthesis of Tetracyclic Spiroindolines,  J. Am. Chem. Soc., 2014, 136, 6900-6903, 2014, 通讯作者
(19) Highly Enantioselective [3+3] Cycloaddition of Aromatic Azomethine Imines with Cyclopropanes Directed by π–π Stacking Interactions, Angew. Chem. Int. Ed., 2013, 52, 1452-1456, 2013, 通讯作者
(20) A Highly Efficient and Enantioselective Intramolecular Cannizzaro Reaction under TOX/Cu(II) Catalysis, J. Am. Chem. Soc., 2013, 135, 16849-16852, 2013, 通讯作者
(21) Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with Donor-Acceptor Cyclopropanes: Accessing 3a-Hydroxy [n.3.0]Carbobicycles, Angew. Chem. Int. Ed., 2013, 52, 4004-4007, 2013, 通讯作者
(22) Copper-Catalyzed Highly Enantioselective Cyclopentannulation of Indoles with Donor–Acceptor Cyclopropanes, J. Am. Chem. Soc. 2013, 135, 7851-7854, 2013, 通讯作者
(23) Highly Diastereo- and Enantioselective Cyclopropanation of 1,2-Disubstituted Alkenes, Angew. Chem. Int. Ed., 2012, 51, 8838-8841, 2012, 通讯作者
(24) Tridentate Ligands and Beyond in Group IV Metal α-Olefin Homo-/co-polymerization Catalysis, Chem. Soc. Rev., 2012, 41, 4484-4510, 2012, 通讯作者
(25) A Chiral Cage-like Copper(I) Catalyst for Highly Enantioselective Synthesisof 1,1-Cyclopropane Diesters, Angew. Chem. Int. Ed., 2012, 51, 11620-11623, 2012, 通讯作者
(26) Tunable Carbonyl Ylide Reactions: Selective Synthesis of Dihydrofurans and Dihydrobenzoxepines, Angew. Chem. Int. Ed., 2011, 50, 7874-7878, 2011, 通讯作者
(27) Asymmetric Nazarov Reaction Catalyzed by Chiral Tris(oxazoline)/Copper(II), Angew. Chem. Int. Ed., 2010, 49, 4463-4466, 2010, 通讯作者
(28) Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds, J. Am. Chem. Soc., 2009, 131, 4192-4193, 2009, 通讯作者
(29) [O-NSR]TiCl3-Catalyzed Copolymerization of Ethylene with Functionalized Olefins, Angew. Chem. Int. Ed., 2009, 48, 8099-8102, 2009, 通讯作者
(30) Ylide-Initiated Michael Addition-Cyclization Reactions beyond Cyclopropanes, Acc. Chem. Res., 2008, 41, 937-948, 2008, 通讯作者
(31) Phosphine-Triggered Synthesis of Functionalized Cyclic Compounds, Chem. Soc. Rev., 2008, 37, 1140-1152, 2008, 通讯作者
(32) Tandem Michael Addition/Ylide Epoxidation for the Synthesis of Highly Functionalized Cyclohexadiene Epoxide Derivatives, J. Am. Chem. Soc., 2008, 130, 5408-5409, 2008, 通讯作者
(33) Phosphine Catalyzed Intramolecular Formal [3+2] Cycloaddition for the Highly Diastereoselective Synthesis of Bicyclo[n.3.0] Compounds, Angew. Chem. Int. Ed. 2007, 46, 5951-5954, 2007, 通讯作者
(34) Highly Enantioselective and Diastereoselective Cycloaddition of Cyclopropanes with Nitrones and Its Application in the Kinetic Resolution of 2-Substituted Cyclopropane-1,1-dicarboxylates, Angew. Chem., Int. Ed., 2007, 46, 3918-3921, 2007, 通讯作者
(35) Iron Porphyrin-Catalyzed Olefination of Ketenes with Diazoacetate for the Enantioselective Synthesis of Allenes, J. Am. Chem. Soc., 2007, 129, 1494-1495, 2007, 通讯作者
(36) Enantioselective Synthesis of Vinylcyclopropanes and Vinylepoxides Mediated by Camphor-Derived Sulfur Ylides: Rationale of Enantioselectivity, Scope, and Limitation, J. Am. Chem. Soc., 2006, 128, 9730-9740, 2006, 通讯作者
(37) The Michael Addition-Elimination of Ylides to ?,?-Unsaturated Imines. Highly Stereoselective Synthesis of Vinylcyclopropanecarbaldehydes and Vinylcyclopropylaziridines, J. Am. Chem. Soc., 2005, 127, 12222-12223, 2005, 通讯作者
(38) The Development and Application of Chiral Trisoxazolines in Asymmetric Catalysis and Molecular Recognition, Chem. Soc. Rev., 2005, 34, 664-676, 2005, 通讯作者
(39) Controllable Diastereoselective Cyclopropanation. Enantioselective Synthesis of Vinylcyclopropanes via Chiral Telluronium Ylides, J. Am. Chem. Soc., 2003, 125, 13030-13031, 2003, 通讯作者
(40) Sidearm Effect: Improvement of the Enantiomeric Excess in the Asymmetric Michael Addition of Indoles to Alkylidene Malonates, J. Am. Chem. Soc., 2002, 124, 9030-9031, 2002, 通讯作者
(41) A Novel Chiral Sulfonium Yilde: Highly Enantioselective Synthesis of Vinylcyclopropanes, J. Am. Chem. Soc., 2002, 124, 2432-2433, 2002, 通讯作者

科研活动

   
科研项目
( 1 ) 基于金属催化的选择性控制, 主持, 国家级, 2010-01--2013-12
( 2 ) 调控有机合成反应选择性的新方法, 主持, 国家级, 2010-01--2013-12
( 3 ) 交联聚乙烯(PEX)等专用料制备关键技术及产业示范, 主持, 国家级, 2012-01--2014-12
( 4 ) 化学键活化与可控性重组研究, 主持, 国家级, 2012-01--2014-12
( 5 ) 烯烃与烷烃的转化与应用研究, 主持, 部委级, 2012-01--2014-12
( 6 ) 烯烃和烷烃高效转化的若干问题研究, 主持, 部委级, 2013-01--2015-12
( 7 ) 基于过渡金属催化的聚合物材料制备及应用研究, 主持, 部委级, 2012-10--2016-06
( 8 ) 化学键活化与可控性重组研究, 主持, 国家级, 2015-01--2017-12
( 9 ) 基于Csp3-Csp3(H)键断裂与重组的有机合成新反应, 主持, 国家级, 2015-01--2019-12
( 10 ) 环丁烯并碳硼烷和烯基碳硼烷的合成及不对称转化, 主持, 国家级, 2015-01--2018-12
( 11 ) 基于低碳烃资源的碳循环利用, 主持, 部委级, 2016-07--2020-12
( 12 ) 液态聚烯烃的高效合成, 主持, 国家级, 2017-01--2021-12
( 13 ) 基于碳碳键可控转化的物质创制, 主持, 省级, 2017-09--2018-08
( 14 ) 新一代润滑基础油及相关技术, 主持, 部委级, 2019-01--2019-12
参与会议
(1) Quick Construction of Polycyclic Spiroindoline via a Tandem strategy,2015-06,唐勇 
(2) 边臂策略在对映选择性远程控制的应用,2014-09,唐勇 
(3) Asymmetric Ring-opening and Transformations of Donor-Acceptor Cyclopropanes,2014-09,唐勇 
(4) Sidearm Strategy for Catalysts in the Remote Control of Enantioselection and Related,2014-08,唐勇 
(5) Sidearm Effects in the Remote Control of Enantioselection and Related Based on Bisoxazolines,2014-05,唐勇 
(6) Asymmetric Catalysis and Olefin Polymerization,2014-04,唐勇 
(7) 边臂调控-聚烯烃催化剂的设计与应用,2014全国先进催化技术发展与应用及工艺创新研讨会,2014-03,唐勇 
(8) Sidearm Approach to Catalysts in Olefin Polymerization,2014-03,唐勇 
(9) The Asymmetric Ring-Opening Reactions of D-A Cyclopropanes and Related,2013-12,唐勇 
(10) Copolymerization of Ethylene with Polar Olefin Based on Titanium Catalysts,2013-10,唐勇 
(11) Sidearm Approach to Catalysts in Asymmetric Reactions,2013-07,唐勇 
(12) Sidearm Approach to Catalysts in Asymmetric Reactions,2013-05,唐勇 
(13) Sidearm Approach to Olefin Polymerization Catalysts Based on Titanium Imino-Enolates,2012-08,唐勇 
(14) A new approach to chiral catalysts. sidearm effects and applications,2011-12,唐勇 
(15) Sidearm—Performance Control of Phenoxy-Imine Titanium Complexes in Olefin Polymerization,2011-12,唐勇 
(16) Trisoxazoline in Asymmetric Catalysis,2011-07,唐勇 

 

 


 

 

 

 
 
上一篇: 中国科学院上海药物研究所唐希灿 男 博导 下一篇:中国科学院大气物理研究所陶诗言 男 博导

在线咨询

进入QQ咨询

王老师

微信咨询

杨老师

进入20中科院QQ群

709867297

进入20中科大QQ群

680149146

友情链接

科大科院考研网版权所有 © 2020-2022 皖ICP备2021018242号